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Advanced Materials Portfolio
 Healable
Resins
CRG is currently developing a self-healing
version of shape memory polymer (SMP) called Veriflex®
EH. This healable SMP resin will enable increased survivability
for manned and unmanned air vehicles, spacecraft, habitats for
space exploration missions, automobiles, and more.
Veriflex EH is an epoxy-based resin
that will be a direct replacement for current aerospace-grade
epoxy resins. Veriflex EH can be processed using vacuum-assisted
resin transfer molding (VARTM), RTM, or wet lay-up techniques.
CRG is also developing a prepreg formulation.
Veriflex EH uses two healing
mechanisms to restore up to 85% of original mechanical
performance. The first healing mechanism, shape recovery,
brings the cracked or damaged area back into intimate
physical contact. The second healing mechanism, polymer
diffusion, allows long polymer chains to diffuse across
the failure line and restore mechanical integrity. Both
healing mechanisms are thermally activated and are achieved
in less than three minutes.
Possible Applications
• Aerospace structures
• Automobiles
• Marine panels
• Composite structures
Features and Benefits
• 85% recovery of flexural
strength
• Lower cost maintenance and repair
• Longer product life
• Increased survivability
• Tailorability for specific applications
• Custom transition temperatures from
14°C to 105°C (57°F to 221°F)
• Compatibility with standard processing
and manufacturing (VARTM, filament
winding, fiber placement)
Preliminary Data (material is still
in development)
| Property |
Values |
Method |
|
| Thermal |
|
|
|
Glass Transition Temperature
(Tg)
DMA,
Loss Modulus Peak |
56°C |
133°F |
DMA |
|
| Mechanical
(at room temperature) |
|
|
|
| Tensile Strength |
70.7 MPa |
10 Kpsi |
ASTM D638 |
| Tensile Modulus |
3030 MPa |
439 Kpsi |
ASTM D638 |
| Tensile Elongation to Break |
3.5% |
|
ASTM D638 |
| Flexural Stress |
119 MPa |
17 psi |
ASTM D790 |
| Flexural Modulus |
3590 MPa |
520 psi |
ASTM D790 |
|
| Mechanical (30°C/86°F
above Tg) |
|
|
|
| Tensile Strength |
.242 MPa |
35 psi |
ASTM D638 |
| Tensile Modulus |
.00066 MPa |
96 psi |
ASTM D638 |
| Tensile Elongation to Break |
268% |
|
ASTM D638 |
|
| Composite Mechanical (12-ply,
3k, plain weave carbon [0.90] 6) |
|
|
|
| Flexural Stress |
490 MPa |
71Kpsi |
ASTM D790 |
| Flexural Modulus |
33000 MPa |
4,786 Kpsi |
ASTM D790 |
Flexural Stress (post-failure
& healing)
85% recovery of
flexural modulus |
417 MPa |
61 Kpsi |
ASTM D790 |
Flexural Modulus (post-failure
&
healing) 78% recovery of
flexural
modulus |
26000 MPa |
3,770 Kpsi |
ASTM D790 |
|
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