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Glassy Liquid CrystalsGlassy Liquid Crystals

What are Glassy Liquid Crystals?

Glassy liquid crystals (GLC) are an advanced form of liquid crystals that combine the properties of conventional low-molar-mass liquid crystals with the characteristics of polymers. As a new, unique type of liquid crystals, GLC propel liquid crystal technology to new levels, offering nearly perfect circular polarization and selective wavelength reflection. The advantage of GLC is that they can be processed like current liquid crystals and then maintain their optical clarity and molecular alignment when cooled into a solid, stable film.

Uses for these high-performance liquid crystals include flat screen displays, filters, optical storage, and other electro-optic devices.

Specifications

GLC are novel glassy liquid crystals with elevated phase transition temperatures, morphological stability and fatigue resistance for photonic applications. When heated to Tg, GLC undergo a second-order transition from mesomorphic solid into liquid crystal without modifying the molecular order.

Applications include latching electro-optic devices, thin film retarders and compensators, narrow band polarizers, filters, and membranes.

R or S Chiral


Modified (Nematic)

Chemical Names:

R Chiral
1,3,5-Benzenetricarboxylic Acid, 1,3-bis{3-[4-(4'-cyanobiphenyl-4-yloxy)carbonyl}propyl} Ester 5-{4'-[(R)-(+)-1'''-(phenylethyl)]benzamide]-1'-oxy]benzoate-1'-oxy}ethyl Ester

S Chiral
1,3,5-Benzenetricarboxylic Acid, 1,3-bis{3-[4-(4'-cyanobiphenyl-4-yloxy)carbonyl}propyl} Ester 5-{4'-[(S)-(-)-1'''-(phenylethyl)]benzamide]-1'-oxy]benzoate-1'-oxy}ethyl Ester

Modified (Nematic)
Benzene-1,3,5-tricarboxylic acid tris-{3-[4-(4'-cyano-biphenyl-4-yloxycarbonyl)-phenoxy]-propyl} Ester

Properties:

Description Molecular Weight Tg Tc
Modified (Nematic) 1276.3 g/mol 71°C/160°F 325°C/617°F
R Chiral 1308.34 g/mol 83°C/181°F 208°C/406°F
S Chiral 1308.34 g/mol 83°C/181°F 208°C/406°F

Tg = glass transition temperature
Tc = clearing temperature (no longer reflects light)

DSC of R Chiral
DSC of Modified (Nematic)

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